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??????????????(???)-??1-13?????
??? ???????????
?????
??? ??
1.??????????????
1.(CH3)2CHC(CH3)2
2.
CH3CH2CH2CH2CH3
CH3CHCH3
CH3CH(CH3)2
2?3?3?4??????3????4??????
2
3.
1
7
8
CH3CH2C(CH3)2CH2CH3
CH3CHCH3CH2CH3
6
4.CHCHCHCH
322223
3
4
5
CH3
3?3?????? 2?6?????3?6??????
6
5.7
5
3
2
1
4
6
.
8.
67
5
4
2
1
2?5??????2????3?????
7
.
2?4?4?????? 2????3?????
2.?????????????
1?2?2?3?3??????2?2?3??????
CH3CH3
CH3
CH2CH3
33
CH3
CH32CH2CH2CH3
3
3? 2?2?4?????? 4?2?4?????4?????
CH3
CH333
CH3CH3
CH3CHCH2CCH2CH2CH3
3
5? 2????3????? 6??????
CH3
CH3CHCHCH2CH2CH3
2CH3
CH3CH2CHCH2CH3
2CH3
7?????????? 8???????????
CH3CHCH(CH3)2
2CH3
CH3CH2CHC(CH3)3
CH2CHCH3
CH3
3.???????????????????????
1
1.
1
00
34
3
2
1
00
1
2CH3
1
2CH3CH3
1
CH
3
2.
1
3323)
33
3
4.1.
1
2.
3.
4.
5.
6.
5.????????????????????????
(1) 2?3??????(2) ??? (3) 2????? (4) ??? (5) 2?????
??2?????>???> 2?????>2?3??????> ???
????????????????????????????????????????????????????????????????
6.?????????????????????????????????????????????????? ?1? CH 3-CH3
?2? (CH3)3C-C(CH3)3
CH3
3
CH3
CH3CH3
CH3
H
HHH
?32 3HCH3HHH
H
7.?Newmann?????1?2???????????????????????????
??
Br
HH
Br
???????
HH
BrBr
HH
HH??????
??? ????
8.?????????????????????????????
??
Cl1? ???????? 3
H3C
H3CH3H
2?
CH3H
C2H5C2H5
H3
HC2H5
CH3
H5H
3
??
CH3H
????????
Cl3?
CH3Cl
H
3H
CH3
4?
CH3H
3
2H5
H
H
C2H5
C2H5H
????????
3
3
????????
5?
6
?????
9.??????????72?????1????????????2???????????3???????????4?????????????????????? ?: ??n????? 12n+2n+2=72,n=5
10. ?????????????86?????
?1?????????2???????? ?3?????????4???????? ??????86???????C6H14
CH3CH3
CH33
CH3
CH3
CCH3
CH3
CH3CH2CH2CH3
3
CH3CHCH2CH2CH3
CH2CH3
12. ??CH3CH3 + Cl2
3CH2Cl??????????? ?1? ???????????????????? ?2? ????????H?? ??????Cl22 Cl
????CH3CH3 + Cl CH3CH2 + HCl
CH3CH2 + Cl 2 3CH2Cl + Cl
????2ClCl2
CH 3CH2 + Cl 3CH2Cl 2CH 3CH2CH 3CH2CH2CH3
?2?CH3CH3 + Cl CH3CH2 + HCl
+435Jk/mol -431 Jk/mol?H1=+4 Jk/mol
??????????????(???)-??1-13?????
09??3??? QQ 34240759
??? ???????????
?????
??? ??
1.??????????????
1.(CH3)2CHC(CH3)2
2.
CH3CH2CHCHCH2CH2CH3
CH3CHCH
3
CH3CH(CH3)2
2?3?3?4??????3????4??????
2
4.
13
65
7
8
CH3CHCH
3
4
CH2CH3
3.
CH3CH2C(CH3)2CH2CH3CH3CH2CHCH2CH2CCH2CH3
CH3
3?3?????? 2?6?????3?6??????
6
5.7
5
23
1
4
6
.
8.
67
3
5
4
2?5??????2????3?????
7
.
2
1
2?4?4?????? 2????3????? 2.?????????????
1?2?2?3?3??????2?2?3??????
CH3CH3
CH3
3
3
CH2CH3
CH3CH3CHCHCH
3
2CH2CH2CH3
3? 2?2?4?????? 4?2?4?????4?????
? - 1 - ? ? 97 ?
CH3
CH3
C
3
CH3
CH3
CH3CHCH2CCH2CH2CH3
CHCH
3
3CH3
5? 2????3????? 6??????
CH3CH3CHCHCH
2CH2CH3
CH3CH2CHCH2CH3
CH2CH3
7?????????? 8???????????
CH3CHCH(CH
CH2CH3
3)2
CH2CH3
CH3CH2CHC(CH3)3
3
CH2CHCH
CH3
3.???????????????????????
1
1
1.
CH3
1
3
2CH3
2
C
4
1
2CH3
1
CH3
1
CH
3
2.
1
3
323)33
4.1.
3
1
2.
3.
4.
5.
6.
? - 2 - ? ? 97 ?
5.????????????????????????
(1) 2?3??????(2) ??? (3) 2????? (4) ??? (5) 2?????
??2?????>???> 2?????>2?3??????> ???
????????????????????????????????????????????????????????????????
6.?????????????????????????????????????????????????? ?1? CH 3-CH3
?2? (CH3)3C-C(CH3)3
CH3
33
CH3
CH3CH3
CH3
H
HH
H
?32 3HHH
HCH3
H
H
7.?Newmann?????1?2???????????????????????????
??
? - 3 - ? ? 97 ?
Br
H
Br
H
H
Br
H
HHBr
HH
??????? ?????? ??? ????
8.?????????????????????????????
??
Cl1? ???????? CH3
H3C
Cl
H
H3
H3C
Cl
CH
H
CH3
H5H
CH3
2?
CH3H
C2H5
HH3
C2H5
??
C2H5
CH3
CH3H
????????
Cll
3?
CH3
H
lH3
H
Cl
CH3
2H5H
H
HC2H5
C2H5H
4?
CH3
????????
HH3
H3
????????
5?
6
?????
9.??????????72?????1????????????2???????????3???????????4?????????????????????? ?: ??n????? 12n+2n+2=72,n=5
? - 4 - ? ? 97 ?
10. ?????????????86?????
?1?????????2???????? ?3?????????4???????? ??????86???????C6H14
CH3CH3
CH3
CHCHH3CH3
CH3
CCH3
CH2CH3
CH3
CH3CH2
CH3
CH3CHCH2CH2CH3
CHCH2CH3
12. ??CH3CH3 + Cl2
3CH2Cl??????????? ?1? ???????????????????? ?2? ????????H?? ??????Cl22 Cl
????CH3CH3 + Cl CH3CH2 + HCl
CH3CH2 + Cl 2 CH3CH2Cl + Cl
????2ClCl2
CH 3CH2 + Cl 3CH2Cl
? - 5 - ? ? 97 ?
??????????????(???)-??1-13?????1
??? ???????????
?????
??? ??
1.??????????????
1.(CH3)2CHC(CH3)2
2.
CH3CH2CH2CH2CH3
CH3CHCH3
CH3CH(CH3)2
2?3?3?4??????3????4??????
2
3.
1
7
8
CH3CH2C(CH3)2CH2CH3
CH3CHCH3CH2CH3
6
4.CHCHCHCH
322223
3
4
5
CH3
3?3?????? 2?6?????3?6??????
6
5.7
5
3
2
1
4
6
.
8.
67
5
4
2
1
2?5??????2????3?????
7
.
2?4?4?????? 2????3?????
2.?????????????
1?2?2?3?3??????2?2?3??????
CH3CH3
CH3
CH2CH3
33
CH3
CH32CH2CH2CH3
3
3? 2?2?4?????? 4?2?4?????4?????
CH3
CH333
CH3CH3
CH3CHCH2CCH2CH2CH3
3
5? 2????3????? 6??????
CH3
CH3CHCHCH2CH2CH3
2CH3
CH3CH2CHCH2CH3
2CH3
7?????????? 8???????????
CH3CHCH(CH3)2
2CH3
CH3CH2CHC(CH3)3
CH2CHCH3
CH3
3.???????????????????????
1
1.
1
00
34
3
2
1
00
1
2CH3
1
2CH3CH3
1
CH
3
2.
1
3323)
33
3
4.1.
1
2.
3.
4.
5.
6.
5.????????????????????????
(1) 2?3??????(2) ??? (3) 2????? (4) ??? (5) 2?????
??2?????>???> 2?????>2?3??????> ???
????????????????????????????????????????????????????????????????
6.?????????????????????????????????????????????????? ?1? CH 3-CH3
?2? (CH3)3C-C(CH3)3
CH3
3
CH3
CH3CH3
CH3
H
HHH
?32 3HCH3HHH
H
7.?Newmann?????1?2???????????????????????????
??
Br
HH
Br
???????
HH
BrBr
HH
HH??????
??? ????
8.?????????????????????????????
??
Cl1? ???????? 3
H3C
H3CH3H
2?
CH3H
C2H5C2H5
H3
HC2H5
CH3
H5H
3
??
CH3H
????????
Cl3?
CH3Cl
H
3H
CH3
4?
CH3H
3
2H5
H
H
C2H5
C2H5H
????????
3
3
????????
5?
6
?????
9.??????????72?????1????????????2???????????3???????????4?????????????????????? ?: ??n????? 12n+2n+2=72,n=5
10. ?????????????86?????
?1?????????2???????? ?3?????????4???????? ??????86???????C6H14
CH3CH3
CH33
CH3
CH3
CCH3
CH3
CH3CH2CH2CH3
3
CH3CHCH2CH2CH3
CH2CH3
12. ??CH3CH3 + Cl2
3CH2Cl??????????? ?1? ???????????????????? ?2? ????????H?? ??????Cl22 Cl
????CH3CH3 + Cl CH3CH2 + HCl
CH3CH2 + Cl 2 3CH2Cl + Cl
????2ClCl2
CH 3CH2 + Cl 3CH2Cl 2CH 3CH2CH 3CH2CH2CH3
?2?CH3CH3 + Cl CH3CH2 + HCl
+435Jk/mol -431 Jk/mol?H1=+4 Jk/mol
????????????(???)-??1-13?????????????
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发表于 2019-9-13 23:46:11